Lets put it this way: during World War II, the Germans were very interested in using it in self-igniting flamethrowers, but found it too nasty to work with. For dealing with this situation, I have always recommended a good pair of running shoes.". Screen capture done with Camtasia Studio 4.0. After reading this youre probably curious about what possible purpose this chemical could serve that doesnt involve trying to recreate a scene from a Michael Bay movie. [F-].F [Cl++] Reacts with benzene, toluene, ether, alcohol, acetic acid, selenium tetrafluoride, nitric acid, sulfuric acid, alkali, hexane. Or an explosion. This is a concept invented by the American meteorologist. Surely the nuclear reaction has more energy than any sort of oxidizing, no matter how intense or quick. Simple Things theme by Dan Hauk. John Howard, M.D. Well made ships will have self sealing compartments to deal with hull breaches, so you might do some damage to the area directly adjacent to the impact site. One approach is to mix fluorine and oxygen gas inside a vessel heated to 700 C. We're in space having a battle, one can logically assume that the automation of that process on a small scale inside of a warhead is plausible - possibly not practical, but plausible. As an example of the kind of devastation chlorine trifluoride can have, you only need to consider what happened when almost a ton of this stuff was accidentally spilled inside of a warehouse in the 1950s. I mean, maybe? (The list of people who were blown up or poisoned while trying to do so is impressive). Or it's just banned by acting rules of engagement. It must have been one helluva weapon if even Hitler didn't use it (Spoiler Alert: It was). . A planet's density tells us more information than its size. If, however, this coat is melted or scrubbed off, and has no chance to reform, the operator is confronted with the problem of coping with a metal-fluorine fire. It is also hypergolic with such things as cloth, wood, and test engineers, not to mention asbestos, sand, and water with which it reacts explosively. We may earn a commission from links on this page. With phosphorus, it yields phosphorus trichloride (PCl3) and phosphorus pentafluoride (PF5), while sulfur yields sulfur dichloride (SCl2) and sulfur tetrafluoride (SF4). One that I want to point out is that for this weapon to be effective you must first hit an enemy with the shell. No leather suits this time and (interestingly) no earplugs. When you compare the chemical energy stored in your ClFl3 to the kinetic energy required to accomplish the above, we don't really add much. Chlorine trifluoride is one of the most horrifying substances on Earth. only a scrap of plan/data left). This liquid chemical is so corrosive that it can make practically anything burst into flames on contact. . Image by Ken Wilcox under Creative Commons license. AAAS is a partner of HINARI, AGORA, OARE, CHORUS, CLOCKSS, CrossRef and COUNTER. You'll be continuously tested by this game and it takes its forebears' core mechanics and adds them neatly into a new-but-familiar mix of action and strategy. Sensory loss has a profound effect on millions of peoples everyday lives. Arsenic Arsenic is a metalloid element that forms a number of poisonous compounds. Call me The Terrible, or terry if you like. Is a particle accelerator weapon feasible? The problem with that idea is how dangerous this substance is to create and work with. Chlorine trifluoride is one of the most horrifying substances on Earth. A design to accomplish this could have an armor penetrating exterior, then detonate and scatter a bunch of smaller sealed copper spheres like a shotgun blast that would ideally breach the inner walls and then combust. It is an extremely strong oxidant and decomposes into oxygen and fluorine even at 160 C (113 K) at a rate of 4% per day its lifetime at room temperature is thus extremely short. Yes, a ClFL3 fire in a critical area would be devastating on a ship. Handling concerns, however, severely limit its use. Would it be possible to use chlorine trifluoride as the payload of an artillery shell? It remains, with its chemical relatives, off in a part of chemical science that's safe from human exploitation. Chlorine Trifluoride (ClF3) SC (Semiconductor) is a nearly colorless gas with an irritating odor similar to chlorine or mustard with an extremely low odor threshold. I dropped the wrench and blew up the missile!" The careless. in tempus justo mattis vel, tristique porta. It is extremely reactive with most inorganic and organic materials, and will combust many otherwise non-flammable materials without any ignition source. It also has a nice fat density, about 1.81 at room temperature. 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Fe+3 then reacts with OH- of water forming Fe(OH)3 a brown ppt and H+ of water reacts with the remaining Cl- to make the aqueous solution acidic by forming HCl. What is the hardest part of being a scientist. Why is Noether's theorem not guaranteed by calculus? Oxygen or ozone shells would do same thing, although not as intense. The scientific basis, toxicologic data, and risk assessment approach used to derive the IDLH value are summarized to ensure transparency and scientific credibility. Chlorine trifluoride has been investigated as a high-performance storable oxidizer in rocket propellant systems. If you've seen a shooting star on a recent stargazing jaunt, you've spotted the very beginning of the Orionids meteor shower. Gases can cause rapid suffocation because of oxygen deficiency; store . This post has been republished with permission from TodayIFoundOut.com. because of the formation of a thin film of insoluble metal fluoride which protects the bulk of the metal, just as the invisible coat of oxide on aluminium keeps it from burning up in the atmosphere. Generally, cotton and wool are readily available and cyanoacrylate is always a good thing to have on hand in first aid kits, due to its wound sealing ability. It doesn't look much better if your shell breaches the hull in a shallow manner either. ), tetrafluorohydrazine (how on Earth. If it's not perfectly treated, then kaboom goes the vessel. However, by the time it was captured by the advancing Red Army in 1945, the factory had produced only about 30 to 50 tonnes, at a cost of over 100 German Reichsmark per kilogram.a N-Stoff was never used in war.[18][19]. The most spontaneously reactive species are usually not spontaneously produced themselves. Chlorine trifluoride is such an effective oxidizer that it can even potentially set fire to things that have seemingly already been burned up, like ash or spent charcoal. Together, these occasional entries make up the most entertaining and terrifying science-related blog on the internet. "Until they blow up", you say. Dang! For dealing with this situation, I have always recommended a good pair of running shoes.[17]. Really, how often have we heard the "but mutagenic weapons have been banned by all civilized species!" Language links are at the top of the page across from the title. A few of the other things known to not react with chlorine trifluoride include nitrogen, the inert gases and polychlorotrifluoroethylene. It can be kept in some of the ordinary structural metals-steel, copper, aluminium, etc.-because of the formation of a thin film of insoluble metal fluoride which protects the bulk of the metal, just as the invisible coat of oxide on aluminium keeps it from burning up in the atmosphere. To anyone asking why anyone would be so idiotic, Dr. Lowe is with you: Elemental fluorine has commanded respect since well before anyone managed to isolate it, a process that took a good fifty years to work out in the 1800s. There's a small leak in a storage unit, and chlorine trifluoride reaches a nearby surface, immediately starting a toxic reaction that will kill many people on the ship because they're trapped in space and have nowhere to hide. As a gas, chlorine trifluoride is colourless and has a notably sweet and pungent odour not dissimilar from pool chlorine. Some of this, under ordinary circumstances, might be considered protective equipment. And countermeasures similar to those of ICBMs can be built into ClF3 factory-bomb (decoys, antiradar measures, etc.). It's been used in the semiconductor industry to clean oxides off of surfaces, but, in general, it's probably too powerful for its own good. They had four explosions at -78C, while the fifth run (persistence!) "Another thing I always enjoy in these papers is the list of recommended protective gear. Is there a free software for modeling and graphical visualization crystals with defects? (An indexing machine is a rotating assembly with work-holders around its periphery that advances the work in steps through a series of stations followed by a pause during which operations at each station are carried out on the Page 12 of 31 Handbook of Advanced Lighting Technology DOI 10.1007/978-3-319-00295-8_1-1 # Springer International . 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